Group of

Prof. Wei Lu

 
 
Prof. Wei Lu

 
Last updated on
03/09/2006

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Mechanical Engineering, University of Michigan
Research Introduction Modeling Simulation Results
   
 
Concept Configurational Force  Phase Separation  Coarsening  Refining  Surface Stress
Model Introduction  Energetics  Kinematics  Kinetics  Variational Statement&Equation  Length Scale  Normalized Equation

 

Scales and Parameters

    A comparison of the first two terms in the parenthesis in Eq. (15) defines a length

 

          

(16)

    In the Cahn-Hilliard model this length scales the distance over which the concentration changes from the level of one phase to that of the other.  Loosely speaking, one may call b the width of the phase boundary.   The magnitude of  is on the order of energy per atom at a phase boundary.  Using magnitudes ,  and  (corresponding to T = 400 K), we have b ~ 0.6 nm.

 

The competition between coarsening and refining (i.e., between the last two terms in Eq. 15) defines another length:

 

          

(17)

Young’s modulus of a bulk solid is about .  According to Ibach, the slope of the surface stress is on the order . These magnitudes, together with , give .  The following numerical simulation shows that the equilibrium phase size is on the order ~.  This broadly agrees with experimentally observed phase sizes.

      

From Eq. (15), disregarding a dimensionless factor, we note that the diffusivity scales as .  To resolve events occurring over the length scale of the phase boundary width, b, the time scale is , namely

 

          

(18)

 

 

 

 

 

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