We are conducting the simulation on a thin film with thickness 10. The
reasons we do not simulate from the substrate, i.e. the thin film thickness
is 0, are the following:
In real experiments of QD growth, the very early stage of the material
deposition does not involve the formation of islands. This is due to the
wetting potential between the substrate atoms and the deposited atoms. The
transition to island nucleation occurs after the atoms accumulate to a
critical thickness.[6] And the processes after this critical time are more
important to the formation of QDs.
On the other hand, if you are interested in this early stage, updated
meshing codes for Abaqus (more elements are added in thickness) should be
generated after the film is getting thicker.
1. Surface flattening:
The reduction of surface area could decrease the free energy of the system.
Result shows the surface flattening process from a rough surface. The
elastic energy is not considered here.
2. Nucleation process:
The elastic energy is considered here. An initial rough surface evolves into
several islands. The surface energy and bulk free energy difference are both
considered. Noting that certain coarsening process occurs due to the
existence of surface energy.
3. Growth process:
Because of the limited elements we use, we are not able to simulate the
growth process of QDs based on the result of 3. Here we manipulate several
nucleation sites on the thin film, i.e. several small bumps with amplitude
<0.1 here. Result shows the growth of QDs from small bumps(nucleation sites)
to islands. The condensation/deposition process is purposely constrained to
show the mass conservation of the surface diffusion process. It is clear
that the vicinities of the island are lowed when the QDs are growing.
4. Deposition/Condensation:
Result shows that the
materials are being deposited on the thin film.
Both surface energy and bulk free energy difference are considered.
Without strain energy:
With strain energy: