Group Publications are divided into the areas of

Organometallic Chemistry,

Surface and Interface Chemistry,

and Main Group Polymer Chemistry


Atomic Force Microscopy of Drug Delivery Agents, Lipid Bilayers, and Cell Surfaces

 


49. Tapping Mode Atomic Force Microscopy Investigation of Poly(amidoamine) Core-Shell Tecto(Dendrimers) using Carbon-Nanoprobes.  T. A. Betley, M. M. Banaszak Holl, B. G. Orr, S. Uppulari, D. A. Tomalia, and J. R. Baker Jr., submitted J. Am. Chem. Soc.

48. Tapping Mode Atomic Force Microscopy Investigation of Poly(amidoamine) Dendrimers:  the Effects of Substrate and pH on Dendrimer Deformation.  T. A. Betley, M. M. Banaszak Holl, B. G. Orr, D. R. Swanson, D. A. Tomalia, and J. R. Baker Jr., submitted Langmuir.



Organometallics: Transition Metal Germylene Chemistry


46. Intermolecular C-H Insertions and Cyclization Reactions involving a Stable Germylene.  K. A. Miller, T. W. Watson, J. E. Bender, M. M. Banaszak Holl, J. W. Kampf, in press J. Am. Chem. Soc.

42. Photochemistry of Organometallic Germylenes and Metallacycles.  K. E. Litz, J. E. Bender, R. D. Sweeder, M. M. Banaszak Holl, J. W. Kampf.   Organometallics  2000, 19, 186-189.

37. X-ray Crystallographic and Theoretical Comparison of Ge[2,4,6-(CF3)3C6H2]2 and Ge[N(SiMe3)2]2 as Ligands in (Ph3P)2NiGeX2 Complexes. J. E. Bender, A. J. Shusterman, K. E. Litz, M. M. Banaszak Holl, J. W. Kampf.   Organometallics  1999, 18, 1547.

35. The Active Role of a Germylene Ligand in Promoting Reactions of Pt Complexes with Oxygen and Sulfur Dioxide. K. E. Litz, M. M. Banaszak Holl, J. W. Kampf, Inorg. Chem. 1998, 37, 6461.

34. Ortho(trifluoromethl)aryl Interaction and Stabilization in Hypervalent Germanium Compounds. J. E. Bender, M. M. Banaszak Holl, A. Mitchell, N. J. Wells, J. W. Kampf, Organometallics 1998, 17, 5166.

31. Activation of Arylnitroso Substrates on a Platinum Germylene Complex Facilitating the Formation of New N-C and N-S bonds. K. E. Litz, J. W. Kampf, M. M. Banaszak Holl. J. Am. Chem. Soc. 1998, 120, 7484.

26. Intermediates in the Catalytic Dehydrogenative Coupling of Aryl Germanes. Chemistry - A European Journal 1997, 3, 1793. J. E. Bender, K. E. Litz, D. Giarikos, N. J. Wells, M. M. Banaszak Holl, and J. W. Kampf.

22. Synthesis and Characterization of Ge[(2,4,6)-(CF3)3C6H2]2. Organometallics1997, 16, 2743. J. E. Bender, M. M. Banaszak Holl, and J. W. Kampf.

20. Transition Metal Germylene Complexes as Hydrogenation Catalysts: the Synthesis of a Rare Bisamidegermane. Angew. Chem. Int. Ed. 1997, 36, 496. K. E. Litz, J. E. Bender, and M. M. Banaszak Holl.

14. Synthesis, Structure, and Reactivity of a Platinum Germylene Complex. Organometallics 1995, 14, 5008. K. E. Litz, K. Henderson, R. K. Gourley, and M. M. Banaszak Holl.

Surface and Interface Chemistry:

The Silicon/Silicon Oxide Interface and Cluster Monolayers on Gold




51. Self-limiting Chemical Vapor Deposition of an Ultra-thin Silicon Oxide Film.  K. A. Miller, C. John, K. Z. Zhang, K. T. Nicholson, F. R. McFeely, and M. M. Banaszak Holl, submitted Thin Solid Films.

50.   Reflection-Absorption Infrared Spectroscopy of Si-H Bonds in an Annealed Ultra-thin Silicon Oxide Film.  K. T. Nicholson, K. Z. Zhang, M. M. Banaszak Holl, and F. R. McFeely, submitted Appl. Phys. Lett.

47. A Density Functional Study of the Role ortho-CF3 Groups Play in Stabilizing Germylenes and Related Divalent Group 14 Complexes.  A. J. Shusterman and M. M. Banaszak Holl, submitted Organometallics.

45. A New Infrared and Density Functional Theory Study of Model Silicon/Silicon Oxide Interfaces.  K. T. Nicholson and M. M. Banaszak Holl, submitted Phys. Rev. B.

44.   The Dynamic Nature of Hydridosilsesquioxane Clusters on Gold Surfaces.  K. T. Nicholson, K. Z. Zhang, M. M. Banaszak Holl, F. R. McFeely, U. C. Pernisz.  Langmuir  2000, 16, 8396-8403.

43. Determination of Spherosiloxane Cluster Bonding to Si(100)-2x1 by Scanning Tunneling Microscopy   K. S. Schneider, Z. Zhang,  M. M. Banaszak Holl, B. G. Orr U. C. Pernisz. Phys. Rev. Lett.  2000, 85,  602.

41. H8Si8O12 Clusters on Si(100)-2x1 and Gold:  A Comparitive Infrared Spectroscopic Study.  K. T. Nicholson, M. A. Biscotto, M. M. Banaszak Holl,  Mat. Res. Soc. Symp. Proc 1999,  567, 543-548.

40. The Reaction of H8Si8O12 with a Chromium Oxide Surface:  a model for stainless steel surface modification.  J. N Greeley, S. Lee, M. M. Banaszak Holl.  Appl. Organomet. Chem.  1999, 13, 279-285.

39. Chemisorbtion of H8Si8O12 Clusters on Gold via a Novel Si-H Bond Activation. K. T. Nicholson, K. Z. Zhang, M. M. Banaszak Holl.  J. Am. Chem. Soc.1999, 121,3232.

38.  Nucleation of chemical vapor deposited silicon nitride on silicon dioxide.   M. Copel, P. R. Varekamp, D. W. Kisker, F. R. McFeely, K. E. Litz, M. M. Banaszak Holl.  Appl. Phys. Lett. 1999, 74, 1830.

34. Infrared Study of H10Si10O15 Chemisorbed on Si(100)-2x1. J. N. Greeley, M. M. Banaszak Holl, Inorg. Chem. 1998, 37, 6014.

32. Surface Infrared Studies of Silicon/Silicon Oxide Interfaces Derived from Hydridosilsesquioxane Clusters. J. N. Greeley, L. M. Meeuwenberg, M. M. Banaszak Holl. J. Am. Chem. Soc. 1998, 120, 7776.

31. Extra-Atomic Relaxation and Core-Level Binding Energy Shifts at Si/SiO2 interfaces: the effects of cluster size on physical models. K. Z. Zhang, K E. Litz, M. M. Banaszak Holl, F. R. McFeely. J. Phys. Chem. 1998, 102, 3930.

30. An Infrared Study of H8Si8O12 clusters adsorption on Si(100) surfaces. J. Eng. K. Ragavachari, L. M. Struck, Y J. Chabal, B. E. Bent, M. M. Banaszak Holl, F. R. McFeely, A. M. Michaels, G. W. Flynn, S. B. Christman, E. E. Chaban, G. P. Williams, K. Radermacher, S. Mantl. J. Chem. Phys. 1998, 108, 8680

29. The Reaction of H8Si8O12with a Chromium Oxide Surface: a model for stainless steel surface modification. J. N. Greeley, S. Lee, M. M. Banaszak Holl, Appl. Organomet. Chem.1999, 13, 279.

28. The Role of Second-Neighbor Effects in Photoemission: Are Silicon Surfaces and Interfaces Special? Appl. Phys. Lett. 1998, 72, 46. K. Z. Zhang, K E. Litz, M. M. Banaszak Holl, F. R. McFeely.

27. Construction of Solid/Solid Interface Models using Modular Chemistry: the Si/SiO2 Interface, in Modular Chemistry, edited by J. Michl (Kluwer, Dordrecht, 1997), p. 451. S. Lee, M. M. Banaszak Holl, W. H. Hung, and F. R. McFeely.

25. The Role of Extra-Atomic Relaxation in Determing Si 2p Binding EnergyShifts at Silicon/Silicon Oxide Interfaces. J. Appl. Phys.1997, 82, 2298. K. Z. Zhang, J. N. Greeley, M. M. Banaszak Holl, and F. R. McFeely.

24. Chloroethane Physisorbed on Hydrogenated Si(111): A Test System for the Evaluation of Core Level XPS Assignment Rules at Si/SiO2 Interfaces. Mater. Res. Soc Symp. Proc. 1997, 446, 15. F. R. McFeely, K. Z. Zhang, and M. M. Banaszak Holl.

23. Soft X-ray Si 2p core-level spectra of H8Si8O12 physisorbed on Si(111)-H: additional experimental evidence regarding the binding energy shift of the HSiO3 fragment. Mater. Res. Soc Symp. Proc. 1997, 446, 241. K. Z. Zhang, M. M. Banaszak Holl, and F. R. McFeely.

21. A New Model Silicon/Silicon Oxide Interface Synthesized from H10Si10O15 and Si(100)-2x1. Japanese Journal of Applied Physics 1997, 36, 1622. K. Z. Zhang, L. M. Meeuwenberg, M. M. Banaszak Holl, and F. R. McFeely.

19. Si 2p Core-Level Shifts at the Si(100)-SiO2 Interface: An Experimental Study. Physical Review B, Brief Reports 1996, 54, 7686. K. Z. Zhang, M. M. Banaszak Holl. J. E. Bender IV, S. Lee, and F. R. McFeely

17. An Inquiry Concerning the Principles of Si 2p Core-Level Photoemission Shift Assignments at the Si/SiO2 Interface. Journal of Vacuum Science and Technology B 1996, 14, 2824. F. R. McFeely, K. Z. Zhang, M. M. Banaszak Holl, S. Lee, and J. E. Bender.

15. Photoemission Assignments of HxSiO4-x fragments in the Si/SOx Interface Region. Appl. Phys. Lett.1996, 68, 1081. Sunghee Lee, Mark M. Banaszak Holl, Wei Hsiu Hung, and F. R. McFeely.

12. Synthetic Control of Solid/Solid Interfaces: Analysis of Three New Silicon/Silicon Oxide Interfaces by Soft X-ray Photoemission. J. Am. Chem. Soc. 1994, 116, 11819. S. Lee, S. Makan, M. M. Banaszak Holl, and F. R. McFeely.

11. Core Level Photoemission and the Structure of the Si/SiO2 Interface: a reappraisal. Appl. Phys. Lett. 1994, 65, 1097. M. M. Banaszak Holl, S. Lee, and F. R. McFeely.

8. The Si/SiO2 Interface: New Structures and Well-Defined Model Systems. Phys. Rev. Lett. 1993, 71, 2441. M. M. Banaszak Holl and F. R. McFeely.

Main Group Polymer Chemistry

38. Synthesis and Characterization of a Soluble, Highly Branched Organo Silicon-Nitride Polymer. J. E. Bender, W. Chin, M. M. Banaszak Holl, Chem. Mater.  1999, 11, 154.

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