KubarychGroup
C. R. Baiz, R. McCanne, K. J. Kubarych, J. Am. Chem. Soc. 131 (2009) 13590-13591
Cyclopentadienylmolybdenum(II) tricarbonyl dimer exists in two different equilibrium conformations: trans and gauche. Ultrafast photoexcitation in the ultraviolet cleaves the Mo−Mo bond, permitting observation of the subsequent geminate rebinding reaction (trebinding = 31.6 ps) by monitoring infrared bleach recoveries at frequencies corresponding to the CO stretches of the trans and gauche isomers, the time-resolved measurements revealed that the monomers rebind in the trans configuration only. Further insight into the rebinding reaction was obtained by mapping the full potential energy surface along the reaction coordinate using electronic-structure methods.
This work was mentioned as part of C&E News’ cover story on the 50th anniversary of the laser.
9/3/09